Article ID Journal Published Year Pages File Type
5390032 Chemical Physics Letters 2006 6 Pages PDF
Abstract
The results of a quantum-mechanical study of vibrational relaxation of hydrogen adsorbed on a Si(1 0 0) surface with the MCTDH method are presented. Characteristic times of the system evolution agree well with our previous perturbation theory study. The vibrational population decay is non-exponential, and exhibits recurrences due to finite bath size.
Related Topics
Physical Sciences and Engineering Chemistry Physical and Theoretical Chemistry
Preview
Free vibrational relaxation of H adsorbed on a Si(1 0 0) surface investigated with the multi-configurational time-dependent Hartree method
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