| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 5390141 | Chemical Physics Letters | 2006 | 5 Pages |
Abstract
Magnetic and EPR data suggest the occurrence of photoinduced Valence Tautomerism in a cobalt(III)-polydioxolene polymer. The 1D nature of the system results in a larger amount of cooperativity than previously observed in monomers. Analysis of kinetics data further suggest the existence of a relaxation mechanisms based on phonon assisted tunnelling.
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Authors
Alessandra Beni, Andrea Dei, David A. Shultz, Lorenzo Sorace,