Article ID Journal Published Year Pages File Type
5390760 Chemical Physics Letters 2006 4 Pages PDF
Abstract
We report barriers to internal rotation of the acylimine (peptide) linkage in simple models of mature (immature) forms of the red fluorescent protein DsRed. The results indicate a substantial barrier lowering following acylimine formation, providing prima facie evidence that bond rotation follows acylimine formation in DsRed chromophores.
Related Topics
Physical Sciences and Engineering Chemistry Physical and Theoretical Chemistry
Preview
trans-cis Isomerism and acylimine formation in DsRed chromophore models: Intrinsic rotation barriers
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