| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 5390862 | Chemical Physics Letters | 2006 | 4 Pages |
Abstract
The kinetics of the title reaction was studied in different salt solutions (NaNO3, LiNO3, Ca(NO3)2 and Na2SO4). The results are interpreted as a consequence of ion pairing effects. It has been shown that the anion of the salts is the ion associating with the binuclear complex. This association of the anion produces a less favorable reaction free energy and consequently a diminution of the reaction rate.
Related Topics
Physical Sciences and Engineering
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![Ion pairing effects on the kinetic of the intramolecular electron transfer reaction [FeII(CN)5pzCoIII(NH3)5] â [FeIII(CN)5pzCoII(NH3)5]](/preview/png/5390862.png "First Page Preview: Ion pairing effects on the kinetic of the intramolecular electron transfer reaction [FeII(CN)5pzCoIII(NH3)5] â [FeIII(CN)5pzCoII(NH3)5]")
Authors
F. Muriel, R. Jiménez, P. Pérez-Tejeda, F. Sánchez,