| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 5390936 | Chemical Physics Letters | 2006 | 6 Pages |
Abstract
Nearly a 1000 Xâ¼âBâ¼ transitions of jet-cooled SCCl2 have been measured by stimulated emission pumping. The observed rovibrational band contours cover the 210-330 THz region. A statistical autocorrelation analysis of the spectra answers a key question about the state space model of vibrational energy flow: is the dilution factor Ï, which describes how many eigenstates participate in an optically 'bright' state due to anharmonic mixing, distributed according to a bimodal probability distribution P(Ï) or not? Our SEP data supports a bimodal distribution predicted by state space models.
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Authors
S. Lee, M. Engel, M. Gruebele,