| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 5390986 | Chemical Physics Letters | 2006 | 6 Pages |
Abstract
We report static and ultrafast IR studies of Fe(CN)5NO2â and W(CO)6 in bulk ionic liquids and of ionic liquid reverse micelles. For Fe(CN)5NO2â and W(CO)6 in ionic liquids, the vibrational frequencies appear to scale with solute-solvent interaction strength, but the vibrational energy relaxation (VER) times are longer than in methanol and DMSO. The VER times in the reverse micelles are consistent with a solvation environment that has mixed surfactant and ionic liquid and is more polar than the bulk ionic liquid. These results differ from previous ionic liquid reverse micelle studies.
Related Topics
Physical Sciences and Engineering
Chemistry
Physical and Theoretical Chemistry
Authors
Gerald M. Sando, Kevin Dahl, Jeffrey C. Owrutsky,