| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 5391366 | Chemical Physics Letters | 2008 | 6 Pages |
Abstract
The demethanation of DME by iron can take place on both the quartet and sextet PESs, and along the energetically preferable quartet pathway, the demethanation reaction proceeds through C-O activation rather than the methyl C-H activation; while along the sextet PES, both the C-O and C-H activation could result in the demethanation through relative higher energy barriers.
Related Topics
Physical Sciences and Engineering
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Physical and Theoretical Chemistry
Authors
Ning Ding, Shiguo Zhang, Xiangxia Chen,