Article ID Journal Published Year Pages File Type
5392076 Chemical Physics Letters 2006 5 Pages PDF
Abstract
We have investigated water adsorption on Pt(1 1 1) using chloroform to probe the structure and binding sites available on the ice surface. A stable adsorption site appears, associated with growth of ice crystallites on the (39×39)R16° wetting layer, and disappears slowly as the film grows and loses its registry to the wetting layer. The 39 multilayer consists of ordered crystalline ice nuclei which aggregate progressively into a continuous incommensurate ice as the film grows to ∼40 layers, the entire film and wetting layer restructuring into an oriented bulk ice only for films more than 50 layers thick.
Related Topics
Physical Sciences and Engineering Chemistry Physical and Theoretical Chemistry
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