| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 5394265 | Computational and Theoretical Chemistry | 2012 | 5 Pages |
Abstract
⺠Cyclic alkylaminosilylenes have rather large ÎES-T, ÎEHOMO-LUMO, and Ï
min > 100 cmâ1. ⺠Significant energy barriers prevent these sextet silylene from rearrangement to their corresponding full valence octet isomers. ⺠They show rather high heats of hydrogenation through isodesmic reactions. ⺠They do not dimerize because of high energy barriers. ⺠Their nucleophilicity and electrophilicity are similar to stable silylenes reported.
Related Topics
Physical Sciences and Engineering
Chemistry
Physical and Theoretical Chemistry
Authors
M.Z. Kassaee, H. Zandi, B.N. Haerizade, M. Ghambarian,