Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
5394345 | Computational and Theoretical Chemistry | 2013 | 16 Pages |
Abstract
⺠Stepwise bimolecular mechanism for allenamide isomerization is more favorable than the concerted mechanism. ⺠Carboxylic acid catalyzes the isomerization process through a relay mechanism. ⺠Stereoselectivity can be predicted correctly through bimolecular mechanism. ⺠Regioselectivity can be predicted correctly through bimolecular mechanism. ⺠Self catalysis bimolecular mechanism is applicable for allene isomerization.
Related Topics
Physical Sciences and Engineering
Chemistry
Physical and Theoretical Chemistry
Authors
Atanu Basak, Sampad Narayan Gupta, Kuheli Chakrabarty, Gourab Kanti Das,