Article ID Journal Published Year Pages File Type
5394345 Computational and Theoretical Chemistry 2013 16 Pages PDF
Abstract
► Stepwise bimolecular mechanism for allenamide isomerization is more favorable than the concerted mechanism. ► Carboxylic acid catalyzes the isomerization process through a relay mechanism. ► Stereoselectivity can be predicted correctly through bimolecular mechanism. ► Regioselectivity can be predicted correctly through bimolecular mechanism. ► Self catalysis bimolecular mechanism is applicable for allene isomerization.
Related Topics
Physical Sciences and Engineering Chemistry Physical and Theoretical Chemistry
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