| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 5394346 | Computational and Theoretical Chemistry | 2013 | 10 Pages |
Abstract
⺠Syn-βH elimination in traditional Heck mechanism could not occur for heterocycles. ⺠Base-assisted anti-βH elimination is the most kinetically favored for heterocycles. ⺠Isomerization and synβH elimination and αH elimination and 1,2H shift were not favored. ⺠Carbonate as the base is more beneficial for the anti-βH elimination than the amine.
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Physical Sciences and Engineering
Chemistry
Physical and Theoretical Chemistry
Authors
Shi-Ya Tang, Jie Zhang, Yao Fu,