Article ID Journal Published Year Pages File Type
5394351 Computational and Theoretical Chemistry 2013 6 Pages PDF
Abstract
► Mechanism of cycloaddition between H2GeGe: and formaldehyde has been investigated. ► π Orbital and 4p unoccupied orbital of Ge: in H2GeGe: are object in cycloaddition. ► [2 + 2] Cycloaddition to form a four-membered Ge-heterocyclic ring germylene. ► It further reacts with formaldehyde to form a spiro-Ge-heterocyclic ring compound.
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Physical Sciences and Engineering Chemistry Physical and Theoretical Chemistry
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Ab initio study of mechanism of forming a spiro-Ge-heterocyclic ring compound from H2GeGe: and formaldehyde
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