| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 5394415 | Computational and Theoretical Chemistry | 2013 | 9 Pages |
Abstract
⺠A stereoelectronic effect results in the 5-exo cyclization as the dominant pathway for 4-penteniminyl radical. ⺠The preferred 6-endo cyclization for Ph-substituted 4-penteniminyl radical can be attributed to thermodynamic contribution. ⺠Kinetic and thermodynamic effects on a reaction barrier can be evaluated by Marcus theory.
Related Topics
Physical Sciences and Engineering
Chemistry
Physical and Theoretical Chemistry
Authors
Yu-juan Chi, Hai-tao Yu,