| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 5394459 | Computational and Theoretical Chemistry | 2012 | 12 Pages |
Abstract
⺠The hydrogen-deuterium exchange mechanism for hydrides is analyzed. ⺠The dihydrogen bond determines the selectivity of [1,10-B10H8D2]2â formation. ⺠The transition state for the H/D exchange resembles the non-classical (η2-H2) complex. ⺠The possibilities of η2-H2 complex stabilization is found.
Related Topics
Physical Sciences and Engineering
Chemistry
Physical and Theoretical Chemistry
Authors
Oleg A. Filippov, Natalia V. Belkova, Lina M. Epstein, Agusti Lledos, Elena S. Shubina,