Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
5394471 | Computational and Theoretical Chemistry | 2012 | 6 Pages |
Abstract
⺠Metal-ligand interaction is determined by the electronic nature of the ligand. ⺠Electrostatic contribution is the most affected by the substituent. ⺠Covalent contribution becomes more important for electron withdrawing substituents. ⺠Electron donating substituents increase the p character of the orbital on the ligand.
Related Topics
Physical Sciences and Engineering
Chemistry
Physical and Theoretical Chemistry
Authors
Leonardo M. da Costa, Rosana Marques Amorim, MaurÃcio Tavares de Macedo Cruz, J. Walkimar de M. Carneiro,