Article ID Journal Published Year Pages File Type
5394474 Computational and Theoretical Chemistry 2012 6 Pages PDF
Abstract
► BF3·Et2O-promoted allylboration of aldehydes have been investigated. ► Effect of BF3 in the presence of (R)-pinanediol was studied computationally. ► NBO analysis showed that coordination site is crucial in the reaction pathway. ► Lack of the 1,3-syn-pentane interaction in the TS structure is of importance.
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Physical Sciences and Engineering Chemistry Physical and Theoretical Chemistry
Preview
Investigation of origin of stereo-selectivity of BF3·Et2O-promoted allylboration of aldehydes in the presence of (R)-pinanediol by computational method
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