| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 5394476 | Computational and Theoretical Chemistry | 2012 | 5 Pages |
Abstract
⺠Hyperconjugation energies of alkyl carbanions respond to unsymmetrical p-orbital lobes. ⺠Hybridization indices of p-orbitals show dependency on anionic planarity. ⺠Hyperconjugation energies correlate with extent of anionic p-character. ⺠Orientation of p-orbital and CC* bond axes are important factors in hyperconjugation. ⺠Allylic anions show lower delocalization effects than expected.
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Authors
Ronald R. Sauers,