Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
5394479 | Computational and Theoretical Chemistry | 2012 | 8 Pages |
Abstract
⺠We study theoretically formation mechanism of α-Keggin-type [PW12O40]3â anion. ⺠We obtain various building units in the polymerization processes of PW12 anion. ⺠The starting reaction has been determined through transition state search. ⺠Heteroatom (P) has been introduced in the heterotrimer [PW2O9]â at the second step. ⺠Competition between hetero- and iso-polytungstate polymerizations is essential.
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Physical and Theoretical Chemistry
Authors
Zhong-Ling Lang, Wei Guan, Zhi-Jian Wu, Li-Kai Yan, Zhong-Min Su,