| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 5394543 | Computational and Theoretical Chemistry | 2012 | 7 Pages |
Abstract
⺠We report the first case of cycloaddition of aliphatic substituented bis(enones). ⺠We also provide significant new physical insight into the mechanism. ⺠The reaction proceeds via a 5-membered distonic anion radical intermediate. ⺠The first reaction step prefers a negative RC and the second needs a neutral one.
Keywords
Related Topics
Physical Sciences and Engineering
Chemistry
Physical and Theoretical Chemistry
![A theoretical study on intramolecular anion radical [2Â +Â 2] cyclobutanation of bis(enones): Dramatic effects of the electron-deficient enone partners on the yielding of cyclobutane ring systems](/preview/png/5394543.png "First Page Preview: A theoretical study on intramolecular anion radical [2Â +Â 2] cyclobutanation of bis(enones): Dramatic effects of the electron-deficient enone partners on the yielding of cyclobutane ring systems")
Authors
Jianhua Yuan, Qingli Zhang, Bozhen Chen,