Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
5394554 | Computational and Theoretical Chemistry | 2012 | 9 Pages |
Abstract
⺠Using DFT to study the intramolecular methyl transfer in S-2-alkenyl-dimethylsulfonium ion. ⺠The substituent on the olefinic bond is sensitive to the methyl transfer pathway. ⺠The advantageous transition state always exhibits methyl retention-chair mode.
Related Topics
Physical Sciences and Engineering
Chemistry
Physical and Theoretical Chemistry
Authors
Zhang Xiang,