Article ID Journal Published Year Pages File Type
5394576 Computational and Theoretical Chemistry 2012 7 Pages PDF
Abstract
► Anomeric effect drives the PN rotational barriers. ► The nitrogen lone pair interacts to the anti-bond sigma orbitals. ► PCl σ* orbital interactions drives the rotational barriers. ► MO energy intercross changes the stability and reactivity of molecules.
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Related Topics
Physical Sciences and Engineering Chemistry Physical and Theoretical Chemistry
Preview
Electronic effect on the rotational barriers of PN bond in aminophosphanes. A theoretical approach
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