| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 5394587 | Computational and Theoretical Chemistry | 2012 | 6 Pages |
Abstract
⺠Using DFT to study the intramolecular nitrone-alkene cycloaddition (INAC) of N-3-alkenylnitrone. ⺠The substituent on the olefinic bond is sensitive to the regioselectivity of the INAC reaction. ⺠Both the thermodynamic and intrinsic contributions determine the Z-selectivity. ⺠Aromatic ring in the N-3-alkenylnitrone backbone enhances Z-selectivity and rate of INAC reaction.
Related Topics
Physical Sciences and Engineering
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Physical and Theoretical Chemistry
Authors
Zhang Xiang,