| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 5394684 | Computational and Theoretical Chemistry | 2012 | 11 Pages |
Abstract
⺠Reaction pathways of alkali metal catalyzed Tp-OT hydrolysis are analyzed. ⺠Transition states on either side of intermediate points to (AN + DN) mechanism. ⺠Activation free energy data in water reveal a trend: Li < Na < K. ⺠MED topography used to quantify bond formation/cleavage during hydrolysis.
Keywords
Related Topics
Physical Sciences and Engineering
Chemistry
Physical and Theoretical Chemistry
Authors
Mahboobeh Rahimian, Shridhar P. Gejji,