Article ID Journal Published Year Pages File Type
5394702 Computational and Theoretical Chemistry 2012 8 Pages PDF
Abstract
► We have studied the role of Mg complex in the regioselectivity of the 13DC reactions. ► The reactions have an asynchronous concerted mechanism with a low polar character. ► The steric repulsion plays an important role to display a high C regioselectivity. ► In dichloromethane, the reaction profiles are similar to those obtained in gas phase.
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Related Topics
Physical Sciences and Engineering Chemistry Physical and Theoretical Chemistry
Preview
A DFT study of the role of Lewis acid catalysts in the mechanism of the 1,3-dipolar cycloaddition of nitrile imines towards electron-deficient acryloyl derivatives
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