Article ID Journal Published Year Pages File Type
5394725 Computational and Theoretical Chemistry 2012 6 Pages PDF
Abstract
► We study the reaction mechanism of the small metal cluster IrAg+ mediated C-N coupling. ► Activation of methane by IrAg+ yields the bimetallic cation carbenes IrAgCH2+. ► The reaction IrAgCH2+ with NH3 may result in C-N bond coupling.
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Related Topics
Physical Sciences and Engineering Chemistry Physical and Theoretical Chemistry
Preview
Reaction mechanisms for C-N bond coupling from IrAg+, CH4 and NH3: A density functional theory study
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