| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 5394738 | Computational and Theoretical Chemistry | 2012 | 11 Pages |
Abstract
⺠NH3 and H2O exhibit donor-acceptor bonds to platinum. ⺠OH, NH2, NH and N exhibit covalent bonds to platinum. ⺠N atoms are the cause of platinum poisoning during ammonia oxidation. ⺠Bending modes of adsorbed NH2 and H2O are blueshifted compared to free molecules. ⺠Correct shift in frequency was predicted in comparison with prior calculations.
Related Topics
Physical Sciences and Engineering
Chemistry
Physical and Theoretical Chemistry
Authors
Damilola A. Daramola, Gerardine G. Botte,