| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 5394743 | Computational and Theoretical Chemistry | 2012 | 7 Pages |
Abstract
⺠The reaction undergoes PH activation, CP bond formation and recovery of catalyst. ⺠The CP bond formation is rate-and stereo-determining step. ⺠Deprotonation of HCl is easier than deprotonation of DEHP. ⺠Dimeric Al active species performs higher catalytic efficiency than monomeric one. ⺠The stereoselectivity is controlled by repulsion between adamantanyl and phenyl ring.
Related Topics
Physical Sciences and Engineering
Chemistry
Physical and Theoretical Chemistry
Authors
Weiyi Li, Song Qin, Zhishan Su, Changwei Hu, Xiaoming Feng,