| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 5394931 | Computational and Theoretical Chemistry | 2011 | 7 Pages |
Abstract
⺠The M-Ga bonds in the studied complexes are nearly M-Ga single bond. ⺠The Ï-bonding component of the total orbital contribution is significantly smaller than that of Ï-bonding. ⺠The absolute values of the energy terms increases via the order Mo < W. ⺠Interaction energy as well as bond dissociation energy decrease upon going from X = Cl to X = Me.
Related Topics
Physical Sciences and Engineering
Chemistry
Physical and Theoretical Chemistry
![Structure and bonding analysis of dihalogallyl and dimethylgallyl complexes of molybdenum and tungsten [(η5-C5H5)(CO)3M(GaX2)] (M = Mo, W; X = Cl, Br, I, Me): A theoretical study](/preview/png/5394931.png "First Page Preview: Structure and bonding analysis of dihalogallyl and dimethylgallyl complexes of molybdenum and tungsten [(η5-C5H5)(CO)3M(GaX2)] (M = Mo, W; X = Cl, Br, I, Me): A theoretical study")
Authors
Krishna K. Pandey,