| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 5394991 | Computational and Theoretical Chemistry | 2011 | 6 Pages |
Abstract
⺠We studied the gas-phase activation of methane by Ru+. ⺠A spin crossing occurs from 4RuH(CH3)+ to 2RuH2(CH2)+. ⺠No barrier in excess of the endothermicity of the H2 elimination reaction. ⺠The reactions to produce RuH+ and RuCH3+ are situated at more than 50 kcal/mol.
Keywords
Related Topics
Physical Sciences and Engineering
Chemistry
Physical and Theoretical Chemistry
Authors
Shaoli Liu, Zhiyuan Geng, Yongcheng Wang, Yunfeng Yan,