| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 5395005 | Computational and Theoretical Chemistry | 2011 | 8 Pages |
Abstract
⺠In OsO4-ethene reactions [3 + 2] addition is more feasible than [2 + 2] addition. ⺠OsO2(OH)2-ethene reactions are less feasible than [3 + 2] OsO4-ethene reactions. ⺠In OsO2Cl2-ethene reactions [2 + 2] addition is more feasible than [3 + 2] addition. ⺠Epoxide is not a likely product in OsO2Cl2-ethylene reactions.
Related Topics
Physical Sciences and Engineering
Chemistry
Physical and Theoretical Chemistry
![[3Â +Â 2] Versus [2Â +Â 2] addition of metal oxides across CC bonds: A theoretical study of the mechanisms of oxidation of ethylene by osmium oxide complexes](/preview/png/5395005.png "First Page Preview: [3Â +Â 2] Versus [2Â +Â 2] addition of metal oxides across CC bonds: A theoretical study of the mechanisms of oxidation of ethylene by osmium oxide complexes")
Authors
Richard Tia, Evans Adei,