| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 5395281 | Computational and Theoretical Chemistry | 2011 | 7 Pages |
Abstract
⺠Peroxodisulfuric acid (H2S2O8) forms stable clusters with sulfuric acid (H2SO4). ⺠Replacement of one H2SO4 by H2S2O8 in a pure H2SO4 cluster is thermodynamically favourable. ⺠However, the presence of H2S2O8 does not enhance the addition of further acid molecules to the clusters. ⺠Clustering significantly affects the characteristics of the SO-OS “oxygen bridge” bond.
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Authors
Martta Toivola, Theo Kurtén, Ismael K. Ortega, Markku Sundberg, Ville Loukonen, AgÃlio Pádua, Hanna Vehkamäki,