Article ID Journal Published Year Pages File Type
5395498 Journal of Electron Spectroscopy and Related Phenomena 2017 5 Pages PDF
Abstract
Ultra-thin SiOx layers were inserted between amorphous and crystalline silicon to improve the passivation effect in heterojunction (HJ) solar cells. To investigate the effect of oxide films on passivation, non-destructive and surface sensitive techniques were applied to characterize the surface. X-ray photoelectron spectroscopy (XPS) results revealed the coexistence of intermediate-oxidation states in SiOx layers, where the presence of Si+ and Si2+ correlated to a degradation of the passivation. Meanwhile, the distribution of intermediate-oxidation states was correlated to the surface roughness. In addition, the enhanced passivation layers fabricated in chemical solutions were demonstrated to feature the lowest film density resulting from the presence of a cage-like bonding configuration.
Related Topics
Physical Sciences and Engineering Chemistry Physical and Theoretical Chemistry
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