Article ID Journal Published Year Pages File Type
5395537 Journal of Electron Spectroscopy and Related Phenomena 2017 9 Pages PDF
Abstract
Using the time-dependent closed orbit theory, we study the photodetachment of H− ion in a time-dependent electric field. The photodetachment cross section is specifically studied in the presence of a static electric field plus an oscillating electric field. We find that the photodetachment of negative ion in the time-dependent electric field becomes much more complicated than the case in a static electric field. The oscillating electric field can weaken the photodetachment cross section greatly when the strength of the oscillating electric field is less than the static electric field. However, as the strength of the oscillating electric field is larger than the static electric field, four types of closed orbits are identified for the detached electron, which makes the oscillating amplitude in the photodetachment cross section gets increased again. The connection between the detached electron's closed orbit with the oscillating cross section is analyzed quantitatively. This study provides a clear and intuitive picture for the understanding of the connections between quantum and classical description for the time-dependent Hamiltonian systems and may guide the future experimental research for the photodetachment dynamics in the time-dependent electric field.
Related Topics
Physical Sciences and Engineering Chemistry Physical and Theoretical Chemistry
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