Article ID Journal Published Year Pages File Type
5396372 Journal of Electron Spectroscopy and Related Phenomena 2011 6 Pages PDF
Abstract
A departing photoelectron leaves the molecular ion with a recoil momentum that is distributed between translational motion and the excitation of vibrational and rotational energy levels. In this review, recent measurements of recoil induced effects in core- and valence level photoelectron spectra of free molecules are summarized. The experimental examples are preceded by the outline of a semiclassical model to treat the recoil effects in free molecules.
Related Topics
Physical Sciences and Engineering Chemistry Physical and Theoretical Chemistry
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