Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
5396555 | Journal of Electron Spectroscopy and Related Phenomena | 2010 | 5 Pages |
Abstract
The electronic structures of tri-2-furanyl-phosphine (I) and 1,2-bis(dimethoxyphosphoryl)benzene (II) have been investigated by HeI and HeII UV photoelectron spectroscopy (UPS) and quantum chemical calculations. Their electronic structures are discussed in the framework of their chemical properties and practical applications with special reference to the extent of intramolecular interactions. We have also rationalized the observed increased shielding of phosphorus in 31P NMR spectra of TFP.
Keywords
Related Topics
Physical Sciences and Engineering
Chemistry
Physical and Theoretical Chemistry
Authors
Igor Novak, Branka KovaÄ,