Article ID Journal Published Year Pages File Type
5396842 Journal of Electron Spectroscopy and Related Phenomena 2008 6 Pages PDF
Abstract
A series of Kβ resonant inelastic X-ray scattering (RIXS) spectra of α-Fe2O3 is presented as two-dimensional RIXS maps and analyzed in terms of the Kramers-Heisenberg equation. Genuine lifetime-broadening-suppressed (LBS) spin-selected oscillator strength distributions, which are consistent with Hund's rule, are deduced. It is shown that 2D maps can highlight implications of RIXS results to reveal existences and characteristics of electronic states which are hidden in absorption spectra.
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Physical Sciences and Engineering Chemistry Physical and Theoretical Chemistry
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