Article ID Journal Published Year Pages File Type
5397108 Journal of Electron Spectroscopy and Related Phenomena 2007 4 Pages PDF
Abstract
Ti 3d electronic structure of Ti2O3 has been investigated by means of soft X-ray photoemission spectroscopy (SXES) in the Ti 2p-3d absorption region. In the SXES spectra, the Raman peaks due to the a1g-egπ and a1g-egσ excitations are observed at 1.3 and 3.3 eV below the incident photon energy, respectively. The intensity of the a1g-egσ peak in the SXES spectrum measured between the 2p3/2-3d and 2p1/2-3d absorption peaks depends on the polarization of the incident photon E; the peak observed clearly in case of E parallel to the c-axis, almost disappears in case of E perpendicular to the c-axis.
Related Topics
Physical Sciences and Engineering Chemistry Physical and Theoretical Chemistry
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