Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
5397490 | Journal of Luminescence | 2017 | 9 Pages |
Abstract
A comparative study of the vibrational properties of W(CO)6 has been performed in different solids at cryogenic temperatures focusing on the IR absorption and the vibrational dynamics of the CO stretching mode of the organometallic compound. Guest-host interactions are investigated in doped solids through the linear IR spectroscopy and four-wave mixing techniques at different temperatures. We show how the host nature, the trapping site, the crystallographic ordering affect the properties of the guest molecule and in particular its vibrational dynamics.
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Related Topics
Physical Sciences and Engineering
Chemistry
Physical and Theoretical Chemistry
Authors
Raphaël Thon, Wutharath Chin, Didier Chamma, Alejandro Gutiérrez-Quintanilla, Michèle Chevalier, Jean-Pierre Galaup, Claudine Crépin,