| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 5397757 | Journal of Luminescence | 2017 | 6 Pages |
Abstract
In this paper, a new fluorescence chemosensor 3-[(2-hydroxy-1-naphthyl) methylideneamino]benzoic acid (L) was designed, synthesized and characterized. Fluorescence spectrum and UV-vis spectra show that L exhibits a highly selective and sensitive recognition for HCO3-/CO32- in N,Nâ²-dimethylformamide/water (DMF/H2O, 100/1-10/1, v/v) in pH range of 5-14. The competitive experiments and reversible tests prove the good performance of L. The Jobâ²s plot, 1H NMR titration, and electrospray ionization mass spectrometry (ESI-MS) results show that L and HCO3-/ CO32- form 1:1 complexes. The probable mechanisms and the proposed binding modes were discussed.
Related Topics
Physical Sciences and Engineering
Chemistry
Physical and Theoretical Chemistry
Authors
Changyan Sun, Jiayi Sun, Ping Che, Zhidong Chang, Wenjun Li, Fazheng Qiu,
