Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
5398032 | Journal of Luminescence | 2017 | 13 Pages |
Abstract
A high-luminescence BaZrSi3O9:Eu2+ (BZSE) blue-green-emitting phosphor was successfully synthesized by a gelation method using propylene glycol-modified silane (PGMS). After heat treating under Ar-H2 flow followed by annealing in air, the synthesized phosphor exhibited a strong emission intensity approximately three times stronger than that of commercial BaMgAl10O17:Eu2+ (BAM:Eu2+) along with high internal and external quantum efficiencies of 74.3% and 58.4% at 405Â nm excitation, respectively. We considered the high emission efficiency of the BZSE samples in terms of (1) the self-absorption by the host crystal, (2) change in Eu valence in the phosphor during annealing in air, and (3) stability of Eu substitution at the Ba2+ site in BaZrSi3O9 (BZS). The results indicate that the high emission efficiency of the BZSE samples originated from (1) the reduction in self-absorption caused by the decrease in oxygen deficiency and (2) the suitable quantity (approximately 4Â mol%) of Eu2+ that was retained even after high-temperature annealing in air, which is attributed to the stability of the Eu substitution site in BaZrSi3O9.
Related Topics
Physical Sciences and Engineering
Chemistry
Physical and Theoretical Chemistry
Authors
Tetsufumi Komukai, Yasushi Sato, Hideki Kato, Masato Kakihana,