Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
5398557 | Journal of Luminescence | 2016 | 21 Pages |
Abstract
Single crystals of Nd3+-doped Co-picromerite has been synthesized by the slow evaporation method. After two weeks on hold, the crystals obtained were characterized by different techniques, indeed X-ray powder diffraction (XRPD) shows that these compounds crystallize in the monoclinic system with space group P21/a. Complete dehydration of the double salt was obtained before reaching 200 °C with a phase transition of KS around 570 °C. The IR spectroscopic study confirms the vibrational modes of the sulfate groups and water molecules. Exciting at 473 nm, the emission peaks associated with the 4F5/2â4I9/2, 4F3/2â4I9/2 and 4F3/2â4I11/2 transitions were observed. The luminescence decay curve was analyzed in the frame of the Inokuti-Hirayama model in order to obtain the intrinsic lifetime and the energy transfer parameter among Nd3+ions.
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Physical and Theoretical Chemistry
Authors
A. Souamti, I.R. MartÃn, L. Zayani, M.A. Hernández-RodrÃguez, K. Soler-Carracedo, A.D. Lozano-GorrÃn, E. Lalla, D. Ben Hassen Chehimi,