Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
5398595 | Journal of Luminescence | 2016 | 25 Pages |
Abstract
We report the synthesis and photophysical properties of 4,5-bis(2-((Z)-(3-hydroxynaphthalen-2-yl)methyleneamino)phenylthio)phthalonitrile ligand (SB) and its star-type functional zincphthalocyanine (SB-ZnPc) compound obtained by the condensation of 2,3,9,10,16,17,23,24-octakis-(2-aminophenylthio)zincphthlocyanines (A-ZnPc) and 1-hydroxy-2-naphthaldehyde (HNA). Each compound was purified and characterized by elemental analysis, FTIR, 1H NMR, 13C NMR, UV/vis and MS (Maldi-TOF) spectral data. SB-ZnPc bearing fluorescent SB moieties on the periphery shows selective palladium ion sensing behavior by acting as hard core upon interaction. Electronic spectra of the SB-ZnPc displays pronounced changes in both absorption and fluorescence spectra upon interaction with Pd2+ ion. The fluorescence of the SB-ZnPc compound is effectively quenched by treatment with Pd2+ in THF solution. The solvent effect on the photophysical properties of the SB-ZnPc and interference effect of foreign metal ions were also investigated.
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Authors
M. Nilüfer YaraÅir, Ahmet Aytekin, Mehmet Kandaz, Orhan Güney,