Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
5398879 | Journal of Luminescence | 2015 | 7 Pages |
Abstract
This work first described the linear quenching of LnIII (including LaIII, CeIII, PrIII, NdIII, SmIII, EuIII, GdIII, TbIII, DyIII, HoIII, ErIII, TmIII, YbIII and LuIII) on luminol-dissolved oxygen chemiluminescence system and possible quenching mechanism by flow injection analysis. The general equation of the decrement of CL intensity with LnIII concentration, ÎI=AlnCLn+B, was given and the interaction model of LnIII with luminol, lg[(I0âI)/I]=rlg[Ln]+lgK, was established. The sensitive factor A was found to be linear with the physical parameters (Z, γ±, Eo and ÎHhyd). By plotting A against Z, it could be seen light lanthanides (LL) and heavy lanthanides (HL) presented a good symmetry. The results showed that the reaction of LnIII with luminol was a spontaneous process by the electrostatic force with the association constants K at 106-107 level. The binding constants KD (about 104-105) and the number of binding sites n (about 1) of LnIII (LaIII, EuIII, GdIII, TbIII and LuIII) to bovine serum albumin were first given by FI-CL, and the binding ability of LnIII followed the pattern: LaIII
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Authors
Xiaoqing Liu, Zhuming Wang, Yajuan Li, Yun Zhang, Jie Guo, Jingchan Zhao, Zhenghua Song,