Article ID Journal Published Year Pages File Type
5399345 Journal of Luminescence 2015 6 Pages PDF
Abstract
A 2-substituted-8-hydroxyquinoline ligand (E)-2-[2-naphthyl-ethenyl]-8-hydroxyquinoline (HL) was synthesized and characterized by LC-MS, NMR spectroscopy, elemental analysis and single-crystal X-ray diffraction. Using a solvothermal method, a binuclear complex [Zn2L4] (1) was fabricated by self-assembly of Zn(II) ion with ligand HL. X-ray structural analysis shows that the binuclear Zn(II) units are linked into 1D chain along the b axis via aromatic stacking. The coordination assembly of zinc salt and HL in solutions was investigated by UV-vis and photoluminescence (PL). Additionally, we also studied the thermal stability and photophysical properties of (fluorescent emission and lifetime) complex 1. The experimental results show that the complex 1 emits yellow luminescence in the solid state.
Related Topics
Physical Sciences and Engineering Chemistry Physical and Theoretical Chemistry
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