Article ID Journal Published Year Pages File Type
5399605 Journal of Luminescence 2015 9 Pages PDF
Abstract
The radiative properties of Dy-doped glasses and glass-ceramic phosphors with varying lead and cadmium fluoride content are investigated in the present study for white light emitting applications. The precipitation of cubic lead fluoride phase of 10-18 nm crystallites was determined with the help of x-ray diffraction studies and the nanocrystalline nature was confirmed with scanning electron microscopy studies. The small size of the nanocrystallites enables the fabrication of transparent glass-ceramics which is verified by UV-vis spectroscopic study. The photoluminescence and lifetime measurements indicate towards progressive changes in the Dy3+ ion surroundings and propose enhanced energy transfers taking place post-heat treatments. Finally, CIE chromaticity coordinates are found to lie in the white region proposing the suitability of the present studied materials for color display devices.
Related Topics
Physical Sciences and Engineering Chemistry Physical and Theoretical Chemistry
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