Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
5399912 | Journal of Luminescence | 2014 | 5 Pages |
Abstract
The spectroscopic properties of the six-fold (octahedral) coordinated Eu2+ in SrAl2B2O7 have been investigated. Relevant optical parameters such as the Stokes shift, crystal-field splitting, the centroid shift and the red-shift of the Eu2+ 4f65d1 electronic configuration have been estimated from the experimental data. Further, the Huang-Rhys factor and the effective phonon energy, which are responsible for electron-vibrational interactions are theoretically estimated for the Eu2+ ion in SrAl2B2O7. The low quenching temperature of the luminescence is connected with the thermally induced photoionization of the Eu2+ 4f65d1 electron. A cross-cutting comparative study of the optical properties of octahedrally coordinated Eu2+ in SrAl2B2O7 and in Cs2M2+P2O7 (M2+=Ca2+, Sr2+) is also presented.
Keywords
Related Topics
Physical Sciences and Engineering
Chemistry
Physical and Theoretical Chemistry
Authors
S.J. Camardello, P.J. Toscano, M.G. Brik, A.M. Srivastava,