Article ID Journal Published Year Pages File Type
5399966 Journal of Luminescence 2015 8 Pages PDF
Abstract
The first report of wavelength ratiometric sensing of electron deficient nitroaromatic explosive, 2,5-dinitrophenol (N4) with photoluminescent electron rich Schiff base H2salen (A1) derived from 1,2-ethanediamine and salicyldehyde and related complexes [Zn(salen)]·H2O (A2) and [Ni(salen)]·H2O (A3) in methanol is presented. DFT based optimization reveals that NACs (N1-N5) induce the formation of 1:2 donor-acceptor complexes with the salen based compounds.
Related Topics
Physical Sciences and Engineering Chemistry Physical and Theoretical Chemistry
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