Article ID Journal Published Year Pages File Type
5400375 Journal of Luminescence 2014 5 Pages PDF
Abstract

•YAG:Yb3+ nanoparticles of ca. 10 nm are prepared by glycothermal method at 300 °C.•1029 nm near infrared emission takes place under 940 nm near infrared excitation.•Emission and excitation correspond to 2F5/2→2F7/2 transition of Yb3+.•Subsequent heat treatment causes crystallite growth and elimination of hydroxyl groups, resulting in enhancement of near infrared emission.

Influence of post heat treatment on particulate, structural, surface, and optical properties of YAG:Yb3+ nanoparticles prepared by glycothermal method is studied to understand factors for determining photoluminescence intensity. Characterization is performed on electron microscopy, X-ray diffractometry, infrared absorption spectroscopy, and optical measurements. Near infrared emission under 940 nm near infrared excitation is observed at 1029 nm corresponding to 2F5/2→2F7/2 transition of Yb3+. Subsequent heat treatment causes crystallite growth and elimination of hydroxyl groups, resulting in an enhancement of the near infrared emission.

Related Topics
Physical Sciences and Engineering Chemistry Physical and Theoretical Chemistry
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