Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
5400457 | Journal of Luminescence | 2013 | 9 Pages |
A novel two-step controlled basic water phase method has been developed for synthesizing size-tunable and water-soluble CdTe/Cd(OH)2 core/shell quantum dots with high quantum yield and good stability. The size of the prepared CdTe/Cd(OH)2 core/shell quantum dots can be easily manipulated by varying the concentrations of NaOH solution step by step. The maximal emission wavelengths of the series CdTe/Cd(OH)2 core/shell QDs were from 513Â nm to 610Â nm (emission colors tuned from green to red). The CdTe/Cd(OH)2 core/shell quantum dots not only possess high quantum yield (up to 83%) but also exhibit excellent photostability (being stable after being stored for more than 2 months). The CdTe/Cd(OH)2 core/shell quantum dots were characterized by transmission electron microscopy, high-resolution transmission electron microscopy, X-ray powder diffraction spectrometry, ultraviolet-visible spectrometry and fluorescence spectrometry. The water-soluble nature of the CdTe/Cd(OH)2 core/shell quantum dots offers great potentiality for their chemical and biological applications. This method is easily controlled, low-cost and reproducible. So it is possible to extend this approach to the preparation of other size-tunable inorganic metal hydroxide capped core/shell quantum dots.
â¢CdTe/Cd(OH)2 core/shell quantum dots were synthesized by a novel two-step method.â¢The mechanism relies on varying the concentration of NaOH solution step by step.â¢The prepared quantum dots are characterized by TEM, HRTEM, XRD, UV and FL.â¢The CdTe/Cd(OH)2 core/shell quantum dots show high quantum yield and good stability.