Article ID Journal Published Year Pages File Type
5400457 Journal of Luminescence 2013 9 Pages PDF
Abstract

A novel two-step controlled basic water phase method has been developed for synthesizing size-tunable and water-soluble CdTe/Cd(OH)2 core/shell quantum dots with high quantum yield and good stability. The size of the prepared CdTe/Cd(OH)2 core/shell quantum dots can be easily manipulated by varying the concentrations of NaOH solution step by step. The maximal emission wavelengths of the series CdTe/Cd(OH)2 core/shell QDs were from 513 nm to 610 nm (emission colors tuned from green to red). The CdTe/Cd(OH)2 core/shell quantum dots not only possess high quantum yield (up to 83%) but also exhibit excellent photostability (being stable after being stored for more than 2 months). The CdTe/Cd(OH)2 core/shell quantum dots were characterized by transmission electron microscopy, high-resolution transmission electron microscopy, X-ray powder diffraction spectrometry, ultraviolet-visible spectrometry and fluorescence spectrometry. The water-soluble nature of the CdTe/Cd(OH)2 core/shell quantum dots offers great potentiality for their chemical and biological applications. This method is easily controlled, low-cost and reproducible. So it is possible to extend this approach to the preparation of other size-tunable inorganic metal hydroxide capped core/shell quantum dots.

•CdTe/Cd(OH)2 core/shell quantum dots were synthesized by a novel two-step method.•The mechanism relies on varying the concentration of NaOH solution step by step.•The prepared quantum dots are characterized by TEM, HRTEM, XRD, UV and FL.•The CdTe/Cd(OH)2 core/shell quantum dots show high quantum yield and good stability.

Related Topics
Physical Sciences and Engineering Chemistry Physical and Theoretical Chemistry
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