| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 5401568 | Journal of Luminescence | 2012 | 6 Pages |
Abstract
⺠A fluorescence study of catalytic effect of an 1,3-DC reaction between an acyclic nitrone (N1) with two different dipolarophiles D1 and D2 in toluene. ⺠Yb3+ quenches the fluorescence intensity of N1 more efficiently than Li+. ⺠Li+ shows better interaction with both the two dipolarophiles D1 and D2 hence can accelerate the 1,3-DC reaction rate between N1 and D. ⺠Yb3+ can only be used as good catalyst for the 1,3-DC reaction between N1 and D2. ⺠Spectroscopic findings are rationalized with DFT calculated electrophilicity indices of the reactants.
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Physical Sciences and Engineering
Chemistry
Physical and Theoretical Chemistry
Authors
Tandrima Chaudhuri, Manas Banerjee,